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Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)63+ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation. 相似文献
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DMS (dimethylsulfide), a breakdown product of cellular solutes of many species of macroalgae andphytoplankton plays an important role in regulating global climate and counteracting partly the "greenhouse" effect.In this paper, the advance and prospects of DMS study are reviewed and discussed with respectto DMS sample storage, measurement and importance in regulating global climate and the acidity ofrain and aerosol. 相似文献
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西南岩溶地下水资源开发利用效应与潜力分析 总被引:15,自引:0,他引:15
西南岩溶地区面积78万km2,地下水系统包括裸露岩溶水系统和覆盖-埋藏型岩溶水系统两大类。由于降水丰富、地下岩溶发育,西南岩溶地下水资源丰富,在43万km2调查区内,具有地下水天然资源量1762.82×108m3/a,岩溶地下水允许开采资源量615.70×108m3/a。近年来,通过开展水文地质调查,在地下河、表层岩溶水和蓄水构造岩溶水打井开采方面均取得重要进展,产生了显著的经济和生态环境效应。但由于西南地区岩溶水开发难度大,区域经济落后,西南岩溶地下水的开发利用程度普遍较低,已开采量为98.32×108m3/a,仅占允许开采量的15.97%,剩余地下水潜力资源量517.38×108m3/a。 相似文献
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Stephanie de Villiers 《中国地球化学学报》2006,25(B08):146-146
Acidification is considered the most important one of the primary chemical stress factors that impact on freshwater ecosystems. In unpolluted freshwater systems, the primary controls on the degree of acidification are factors such as the geological substrate of the catchment area, the presence of organic acids secreted by vegetation in the river system, and equilibrium exchange of carbon dioxide with the atmosphere. Anthropogenic factors that can impact on the degree of acidification of freshwater systems include agricultural, mining and industrial activities, either through direct runoff into river systems or through deposition of atmospheric pollutants from these sources. The capacity factors alkalinity and acidity, which represent the acid- and base-neutralizing capacity (ANC and BCN) of an aqueous system, have been used as more reliable measures of the acidic character of freshwater systems than pH. Unlike pH, ANC and BNC are not affected by parameters such as temperature and pressure. Therefore, ANC has been employed as a predictor of biological status in critical load assessments. Freshwater systems with ANC's eq/L isμeq/L are considered sensitive to acidification, ANC=0 μbelow 150 commonly used as the predictor for fish species such as trout in lakes, and an eq/L as more realistic for streams. Acid-neutralizing capacity μANC value of 40 (ANC) can be determined by titration with a strong acid to a preselected equivalence point. Alternatively, it can be calculated as the difference between base cations ([BC]) and strong acid anions ([SAA]): ANC=[BC]- [SAA]=[Ca^2+]+[Mg^2+]+[Na^+]+[K^+]-[SO4^2-]-[NO3^-]-[Cl^-] To date, there has been no attempt to establish the ANC of South Africa's freshwater ecosystems or variability therein, despite the fact that long-term water quality monitoring data exist for all the parameters needed to calculate it according to the above equations. As a result, the relationship between the acid neutralizing capacity of freshwater ecosystems in South Africa and biodiversity factors, such as fish status, is unknown. Results of the first comprehensive (country-wide scale) evaluation of the acid neutralizing capacity of river systems in South Africa will be presented. Long-term monitoring data obtained from the Department of Water Affairs and Forestry (DWAF) from most of South Africa's river systems were used to establish geographic and temporal variabilities in ANC. The results show that the Berg and Breede River systems are most susceptible to acidification, and that geological substrate appears to explain most of the geographic variabilities observed. 相似文献
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Habib Ben Hassine 《Comptes Rendus Geoscience》2006,338(5):329-340
The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca++, Mg++ and K+ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006). 相似文献
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